Duration of local violations of the second law of thermodynamics along single trajectories in phase space.
نویسندگان
چکیده
We define the violation fraction ν as the cumulative fraction of time that the entropy change is negative during single realizations of processes in phase space. This quantity depends on both the number of degrees of freedom N and the duration of the time interval τ. In the large-τ and large-N limit we show that, for ergodic and microreversible systems, the mean value of ν scales as 〈ν(N,τ)〉 ∼ (τN(1/1+α))(-1). The exponent α is positive and generally depends on the protocol for the external driving forces, being α = 1 for a constant drive. As an example, we study a nontrivial model where the fluctuations of the entropy production are non-Gaussian: an elastic line driven at a constant rate by an anharmonic trap. In this case we show that the scaling of 〈ν〉 with N and τ agrees with our result. Finally, we discuss how this scaling law may break down in the vicinity of a continuous phase transition.
منابع مشابه
Experimental demonstration of violations of the second law of thermodynamics for small systems and short time scales.
We experimentally demonstrate the fluctuation theorem, which predicts appreciable and measurable violations of the second law of thermodynamics for small systems over short time scales, by following the trajectory of a colloidal particle captured in an optical trap that is translated relative to surrounding water molecules. From each particle trajectory, we calculate the entropy production/cons...
متن کاملEnergy and Second Law of Thermodynamics Analysis of Shower Cooling Tower with Variation in Inlet Air Temperature
A shower cooling tower (SCT) operates without fill because of salt decomposition on the fill that leads to deterioration of conventional cooling tower performance. This study presents a two-dimensional mathematical model for energy and exergy analysis of multi-diameter droplets and air interaction along with the height of the forced draft SCT, to predict the exit condition of water droplet for ...
متن کاملClassifying the Epilepsy Based on the Phase Space Sorted With the Radial Poincaré Sections in Electroencephalography
Background: Epilepsy is a brain disorder that changes the basin geometry of the oscillation of trajectories in the phase space. Nevertheless, recent studies on epilepsy often used the statistical characteristics of this space to diagnose epileptic seizures. Objectives: We evaluated changes caused by the seizures on the mentioned basin by focusing on phase space sorted by Poincaré sections. Ma...
متن کاملStructure formation and generalized second law of thermodynamics in some viable f(R)-gravity models
We investigate the growth of matter density perturbations as well as the generalized second law (GSL) of thermodynamics in the framework of f(R)-gravity. We consider a spatially flat FRW universe filled with the pressureless matter and radiation which is enclosed by the dynamical apparent horizon with the Hawking temperature. For some viable f(R) models containing the Starobinsky, Hu-Sawicki, Exp...
متن کاملThe Fluctuation Theorem
The question of how reversible microscopic equations of motion can lead to irreversible macroscopic behaviour has been one of the central issues in statistical mechanics for more than a century. The basic issues were known to Gibbs. Boltzmann conducted a very public debate with Loschmidt and others without a satisfactory resolution. In recent decades there has been no real change in the situati...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Physical review. E, Statistical, nonlinear, and soft matter physics
دوره 89 2 شماره
صفحات -
تاریخ انتشار 2014