Duration of local violations of the second law of thermodynamics along single trajectories in phase space.

نویسندگان

  • Reinaldo García-García
  • Daniel Domínguez
چکیده

We define the violation fraction ν as the cumulative fraction of time that the entropy change is negative during single realizations of processes in phase space. This quantity depends on both the number of degrees of freedom N and the duration of the time interval τ. In the large-τ and large-N limit we show that, for ergodic and microreversible systems, the mean value of ν scales as 〈ν(N,τ)〉 ∼ (τN(1/1+α))(-1). The exponent α is positive and generally depends on the protocol for the external driving forces, being α = 1 for a constant drive. As an example, we study a nontrivial model where the fluctuations of the entropy production are non-Gaussian: an elastic line driven at a constant rate by an anharmonic trap. In this case we show that the scaling of 〈ν〉 with N and τ agrees with our result. Finally, we discuss how this scaling law may break down in the vicinity of a continuous phase transition.

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عنوان ژورنال:
  • Physical review. E, Statistical, nonlinear, and soft matter physics

دوره 89 2  شماره 

صفحات  -

تاریخ انتشار 2014